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Home > Encyclopedia > Polybutylene

Polybutylene

Polybutylene structure

Polybutylene 

structure
  • CAS No:

    9003-29-6

  • Formula:

    (C4H8)x

  • Chemical Name:

    Polybutylene

  • Synonyms:

    Butene,homopolymer;Butene,polymers;Amoco 15H;Polybutene SH 015;Polybutylene;Polybutene;Butene polymer;Oronite 6;Chevron 16;Petrofin 100;300H;Polyvis OO;Indopol 1900;PB 2110;Polybuden 300H;Indopol L 10;Chevron 6;Chevron 12;Chevron 18;Oktol 600;Hyvis 7000/45;L 14;LV 50;Polyvis 2000CH;L 14 (polymer);Witron 131;SV 7000;HE 1975;HE 375;Hyvis 3;Hyvis 10;Witron 0200;HE 300;10H;1600A;HV 15E;HV 100;Polybutene HV 100;Polybutene HV 35;HV 35;Polybutene HT-A;VH 100;5H;LV 100;Napvis D 30;Indopol H 25;Nisseki HV 300F;Nisseki HV 15;Nissan Polybutene 06N;Nisseki LV 10;Nisseki LV 50;Polyvis 200SH;Polyvis;Polyvis 06SH;Polyvis 025SH;Polyvis 150SH;HT 300;HV 15;Nisseki LV 100;Nisseki HV 35;Polybutene 100H;Polyvis NC 7000;Polyvis 300H;Polyvis 015N;Polyvis 5N;100H;Nisseki HV 100;Idemitsu Polybutene 5H;RHV 300;Nisseki LV 5;Polyvis 0N;PB 1500;Cosden OSH;Polyvis 06N;Nissan Polybutene 015N;Nissan Polybutene 5N;Indopol H 200;34R;Beaulon P 5040;Nisseki LV 15;Hyvis 5;Glissopal 91051;Glissopal CE 5203;Glissopal 92485;Glissopal 93026;Glissopal 93039;Nisseki HV 1000;Slovis 500;Slovis D 400;Slovis W 800;Glissopal 10;Oloa 9350;Parapol 700;HE 175;PB 4137;Poly-n-butene;ResinKit 22;Glissopal 3251;Ultravis 120;HV 300R;Polyvis 10N;Polybutene PB 5H;Polybutene 2000;Duraflex 8510;Poly SH 2500;Indopol H 40;Napvis DE 10;PB 8510;Polybutene 06N;Tafmer M 2481;Dynapak H 2000;Nissan Polybutene 200SH;200SH;Parapol 450;PB 100R;9037-04-1;11121-22-5;42612-15-7;52012-58-5

  • Categories:

    Cosmetic Ingredient  >  Viscosity Controlling

Description

Polybutylene is composed of linear chains having an isotactic arrangement of ethyl side groups along the chain backbone.

It has a helical conformation in the stable crystalline form.
Polybutylene exhibits high tear, impact, and puncture resistance. It also has low creep, excellent chemical resistance, and abrasion resistance with coilability.


Polybutene is an oily odorless colorless liquid. Floats on water. (USCG, 1999)|Liquid; OtherSolid


Polybutene is an oily odorless colorless liquid. Floats on water. (USCG, 1999)

Polybutylene Basic Attributes

112.216

263.138214

203-452-9

3257

DTXSID2034831

Characteristics

0

0.30

Polybutene is an oily odorless colorless liquid. Floats on water. (USCG, 1999)

0.915 g/cm3

94.3-104.8 °C

293-341 °C

>230 °F

1.708

-196°C

BEGINS TO DECOMPOSE @ ABOUT 350 °C & MONOMER IS ALMOST COMPLETELY REGENERATED

Insoluble in water.

Hydrocarbons, Aliphatic Unsaturated

POLYBUTENE may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas.

Safety Information

NONH for all modes of transport

1

EM9032000

P264, P273, P280, P301+P310, P302+P352, P305+P351+P338, P321, P331, P332+P313, P337+P313, P362, P405, P501

H304

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Polybutene, hydrogenated is an indirect food additive for use as a component of adhesives.

Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]: HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. Substance may be transported hot. For hybrid vehicles, ERG Guide 147 (lithium ion batteries) or ERG Guide 138 (sodium batteries) should also be consulted. If molten aluminum is involved, refer to ERG Guide 169. (ERG, 2016)

|Danger|H304 (38.96%): May be fatal if swallowed and enters airways [Danger Aspiration hazard]|P264, P273, P280, P301+P310, P302+P352, P321, P331, P332+P313, P362, P405, and P501|Aggregated GHS information provided by 1902 companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]: As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet). FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]: ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor-suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean, non-sparking tools to collect absorbed material. LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor, but may not prevent ignition in closed spaces. (ERG, 2016)

Goggles or face shield. (USCG, 1999)|Goggles or face shield.

Carbon dioxide, dry chemical, or foam. Water may be ineffective.

This action promulgates standards of performance for equipment leaks of Volatile Organic Compounds (VOC) in the Synthetic Organic Chemical Manufacturing Industry (SOCMI). The intended effect of these standards is to require all newly constructed, modified, and reconstructed SOCMI process units to use the best demonstrated system of continuous emission reduction for equipment leaks of VOC, considering costs, non air quality health and environmental impact and energy requirements. Polybutene is produced, as an intermediate or a final product, by process units covered under this subpart.

Drug Information

Low toxicity. Vapor may act as a simple asphyxiant in high concentration. (USCG, 1999)

INHALATION: remove victim from exposure. (USCG, 1999)

Vapor may act as a simple asphyxiant in high concentration.

polybutene

Polybutylene Use and Manufacturing

Methods of Manufacturing

The naphtha obtained from petroleum is cracked and fractionated to obtain a mixed gas of butene and butane, which is prevalent at -30~+30℃ with lead chloride and Friedel-Crafts catalyst Polymerization, the polymer is obtained by alkali washing and removing the catalyst with an adsorbent after purification and filtration.

Uses

Hydrophobic material is derivatized to make detergents and anti-rust additives. Adds tack, flexibility and water repellency to adhesives and coatings. Contributes ′cling′ to LLDPE films. Plasticizer for polymers, lubricants and metal-working fluids.


Viscosity adjustors


Lubricants and greases

Production

(1977) 9.35X10+10 GRAMS (SALES)|(1978) 2.11X10+11 GRAMS (EST CONSUMPTION)|1994: 850 million pounds (capacity)|1990: 781 million pounds (capacity)|(1992) No Data

CHEM INT FOR AUTOMOTIVE MOTOR OIL DISPERSANTS, 77%; COMPONENT OF ADHESIVES, CAULKS, SEALANTS & SPECIALTY COATINGS, 12%; GASOLINE ADDITIVE, 5%; ADDITIVE FOR FUNCTIONAL FLUIDS, DIELECTRIC OILS & SPECIALTY LUBRICANTS, 4%; PLASTICIZER & OTHER, 2% (1978 EST)|Lube oil additives and specialty lubes, 68%; caulking and sealant compounds, 9%; industrial lubes, 8%; electrical 5%; adhesives, 3%; exports and misc, 7% (1984)|(1984) 2.46X10+11 g /Demand/|CHEMICAL PROFILE: Polybutenes. Lube oil additives and specialty lubricants, 60%; caulking and sealing compounds, 11%; electrical applications, 7%; industrial lubricants, 6%; adhesives, 6%; exports, 5%; miscellaneous, 5%.|For more Consumption Patterns (Complete) data for POLYBUTENE (7 total), please visit the HSDB record page.

Petrochemical manufacturing|Butene, homopolymer: ACTIVE|XU - indicates a substance exempt from reporting under the Chemical Data Reporting Rule, (40 CFR 711).|1-Butene, polymer with 2-butene and 2-methyl-1-propene, epoxidized: ACTIVE|FRI - indicates a polymeric substance containing no free-radical initiator in its Inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used.|SPRAY APPLICATION OF INDOPOL POLYBUTENE, CONTROLLED THE TWO-SPOTTED SPIDER MITE ON EUONYMUS JAPONICA PLANTS IN A GREENHOUSE STUDY.|Liquid or solid Bronsted and Lewis acids...induce polymerization...by forming carbenium ions. Molecular mass is dependent on many reaction variables, especially temperature: increasing temperature generally results in lower molecular masses

TLC METHOD FOR DETECTING POLYBUTENE CONTAMINATION IN VOLATILE OILS.

EPA Safer Chemical Functional Use Classes -> Polymers|Safer Chemical Classes -> Green circle - The chemical has been verified to be of low concern|Agrochemicals -> Insecticides|Cosmetics -> Binding; Viscosity controlling

Computed Properties

Molecular Weight:112.21
Rotatable Bond Count:1
Exact Mass:112.125200510
Monoisotopic Mass:112.125200510
Heavy Atom Count:8
Complexity:29.2
Defined Bond Stereocenter Count:1
Covalently-Bonded Unit Count:2
Compound Is Canonicalized:Yes

Material

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